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Volume 6 Research & Reviews: Journal of Material Sciences
ISSN: 2321-6212 Materials Physics 2018
August 16-17, 2018
August 16-17, 2018 | London, UK
4th International Conference on
Condensed Matter and Materials Physics
Can superconductivity persist in arbitrarily small particles?
Pushan Ayyub
TIFR, India
The study of superconductivity in nanostructured systems is particularly fascinating due to the existence of a multitude of
length scales, such as the coherence length (ξ) and the penetration depth (λL). Here, we focus on quasi-zero dimensional
superconductors, such as isolated nanoparticles or nanocrystalline solids. In such systems, superconductivity usually persists
down to length scales much smaller than ξ and λL. Ultimately, the lower size limit for superconducting order to exist is set by
the ‘Anderson criterion’, which arises from quantum confinement and is believed to be remarkably accurate and universal. We
report, however, a recent result that questions the validity of the Anderson criterion. We show that phase-pure, nanocrystalline
bcc-Ta remains superconducting (with, TC≈0.9K) down to sizes 40% below the conventional estimate of the Anderson limit
for Ta (4.0nm). Further, both the TC and HC exhibit unusual, non-monotonic size dependences, which we explain in terms of
a complex interplay of quantum size effects, surface phonon softening and lattice expansion. An estimation of TC within first-
principles density functional theory shows that even a moderate lattice expansion allows superconductivity in Ta to persist
down to sizes much below the Anderson limit. This indicates the possibility of bypassing the Anderson criterion by suitable
crystal engineering and obtaining superconductivity at arbitrarily small sizes, an obviously exciting prospect for futuristic
quantum technologies. We take a critical look at how lattice expansion modifies the Anderson limit, an issue of fundamental
interest to nanoscale superconductivity.
Recent Publications
1. S K Mohanta et al. (2016) Size-induced crossover from itinerant to localized magnetism observed for isolated Fe
impurities embedded in different structural polymorphs of silver. Physical Review B. 94:184431.
2. M Dalui et al. (2015) Preferential enhancement of laser-driven carbon ion acceleration from optimized nanostructured
surfaces. Scientific Reports 5:11930.
3. S Chattopadhyay et al. (2015) Local structure, composition and crystallization mechanism of a model two-phase
composite nanoglass. J. Chemical Physics. 144(6):064503.
4. S Bose and P Ayyub (2014) A review of finite size effects in quasi-zero dimensional superconductors. Reports Progress
Physics. 77(11):116503.
Biography
PushanAyyub is a Senior Professor and Chair in the Department of Condensed Matter Physics at the Tata Institute of Fundamental Research, Mumbai, India. He has over
160 publications in the general area of nanoscience. He was a Member of the International Committee on Nanostructured Materials (1998-2008) and is currently a Member
of the Nano Mission Council of the Government of India. He is a Fellow of the Indian National Science Academy. His research interests include the size dependence of
superconductivity and ferroelectricity. He is particularly interested in size-induced structural phase transitions and stabilization of novel crystal structures.
Pushan Ayyub, Res. Rev. J Mat. Sci. 2018, Volume 6
DOI: 10.4172/2321-6212-C2-017